Have you checked on the Accounts if they require Authentication on the outgoing server and if you use encrypted connections i.e. SSL & TLS?

Regards,

Peter

On Fri, Feb 27, 2015 at 8:49 AM, Mathenge Kihoro via skunkworks <skunkworks@lists.my.co.ke> wrote:
morning skunks, am kindly inquiring on how to set up additional accounts on my outlook 2007. the default account is working, whereas the additional accounts are frequently popping up with requests for passwords

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